Issue 7, 1993

Cyclopropanes via nucleophilic attack at the central carbon of (π-allyl)palladium complexes

Abstract

A variety of carboanions (pKa of protonated carbanion [gt-or-equal] 20) combine with (π-allyl)palladium complexes in the presence of N, N, N′, N′, tetramethylethylenediamine (TMEDA)via a new reaction mode, giving functionalized cyclopropanes.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 615-616

Cyclopropanes via nucleophilic attack at the central carbon of (π-allyl)palladium complexes

A. Wilde, A. R. Otte and H. M. R. Hoffmann, J. Chem. Soc., Chem. Commun., 1993, 615 DOI: 10.1039/C39930000615

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