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Issue 4, 1993
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A convenient synthesis of dicarboxylic monoesters using isopropenyl esters: synthesis of oxaunomycin derivatives

Abstract

Reaction of various types of alcohols with a novel type of acylating agent, the isopropenyl esters 2ae in the presence of a catalytic amount of conc. sulfuric acid or toluene-p-sulfonic acid followed by selective deprotection of the terminal ester gives the monoesters 5ai in good yields.

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Article information


J. Chem. Soc., Chem. Commun., 1993, 410-412
Article type
Paper

A convenient synthesis of dicarboxylic monoesters using isopropenyl esters: synthesis of oxaunomycin derivatives

Y. Kita, H. Maeda, F. Takahashi and S. Fukui, J. Chem. Soc., Chem. Commun., 1993, 410
DOI: 10.1039/C39930000410

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