Issue 2, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Aqueous catalytic dimerisation of ethylene: characterization of the reaction intermediates [Ru(CH2[double bond, length half m-dash]CH2)(H2O)5](tos)2 and [Ru(CH2[double bond, length half m-dash]CH2)2(H2O)4](tos)2(tos = toluene-p-sulfonate)

G. Laurenczy  and  A. E. Merbach  

Abstract

It is shown that [Ru(H2O)6]2+ can efficiently catalyse under mild experimental conditions the dimerisation of ethylene in a fully aqueous solution to form butenes ([Z-but-2-ene] : [E-but-2-ene] : [but-1-ene] is 1 : 2.2 : 2.2); the reaction intermediates [Ru(CH2[double bond, length half m-dash]CH2)(H2O)5](tos)2 and [Ru(CH2[double bond, length half m-dash]CH2)2(H2O)]4(tos)2 have been isolated in solid form.

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Article information

DOI
https://doi.org/10.1039/C39930000187
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 187-189

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Aqueous catalytic dimerisation of ethylene: characterization of the reaction intermediates [Ru(CH2[double bond, length half m-dash]CH2)(H2O)5](tos)2 and [Ru(CH2[double bond, length half m-dash]CH2)2(H2O)4](tos)2(tos = toluene-p-sulfonate)

G. Laurenczy and A. E. Merbach, J. Chem. Soc., Chem. Commun., 1993, 187 DOI: 10.1039/C39930000187

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