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Issue 2, 1993
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Acid-catalysed thermal rearrangement of γ,δ-unsaturated ketones

Abstract

Thermal activation of γ,δ-unsaturated ketones (1, 9 and 12) in the presence of a catalytic amount of propionic acid causes a rearrangement to give new γ,δ-unsaturated ketones (2, 10 and 14)via an intramolecular ene reaction followed by a retro-ene reaction.

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Article type: Paper
DOI: 10.1039/C39930000143
J. Chem. Soc., Chem. Commun., 1993, 143-145

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    Acid-catalysed thermal rearrangement of γ,δ-unsaturated ketones

    A. Srikrishna, K. Krishnan and S. Vankateswarlu, J. Chem. Soc., Chem. Commun., 1993, 143
    DOI: 10.1039/C39930000143

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