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Issue 2, 1993
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Novel ring opening and halogen transfer from platinum(II) to phosphorus in the reaction of [PtCl2(CNR)2](R = But,p-MeOC6H4) with the phosphirene ring PPhCPh[double bond, length half m-dash]CPh. Crystal and molecular structure of the dimeric chlorophosphane complex [PtCl(PClPhCPh[double bond, length half m-dash]CPh)(CNBut)]2

Abstract

A new type of ligating behaviour of the phosphirene ring system [graphic omitted]Ph is described, in which novel dimeric platinum(II) Chlorophosphane complexes result from phosphirene ring opening and a Pt–Cl bond-insertion reaction.

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Article type: Paper
DOI: 10.1039/C39930000142
Citation: J. Chem. Soc., Chem. Commun., 1993,0, 142-143

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    Novel ring opening and halogen transfer from platinum(II) to phosphorus in the reaction of [PtCl2(CNR)2](R = But,p-MeOC6H4) with the phosphirene ring PPhCPh[double bond, length half m-dash]CPh. Crystal and molecular structure of the dimeric chlorophosphane complex [PtCl(PClPhCPh[double bond, length half m-dash]CPh)(CNBut)]2

    F. A. Ajulu, P. B. Hitchcock, F. Mathey, R. A. Michelin, J. F. Nixon and A. J. L. Pombeiro, J. Chem. Soc., Chem. Commun., 1993, 0, 142
    DOI: 10.1039/C39930000142

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