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A novel, efficient and general route to protoilludane frameworks via photochemical 1,3-acyl shift of endo-annulated bicyclo[2.2.2]octenones is described.
V. Singh and M. Porinchu, J. Chem. Soc., Chem. Commun., 1993, 134 DOI: 10.1039/C39930000134
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