SCHEDULED MAINTENANCE
The thermolysis of 1-vinylphosphirane 5 at 700°C yields phosphapropyne 7; owing to the existence of an equilibrium between divinylphosphine 6 and 1-vinylphosphirane above 500°C, the same phosphapropyne is also obtained by thermolysis of divinylphosphine.
S. Haber, P. Le Floch and F. Mathey, J. Chem. Soc., Chem. Commun., 1992, 1799 DOI: 10.1039/C39920001799
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