SCHEDULED MAINTENANCE
Supported ruthenium carbido-cluster catalysts ([Ru6C(CO)16Me]–/oxide) selectively produced methanol, dimethyl ether, and formaldehyde in CO–H2, in contrast to the preferential formation of methane and hydrocarbons on supported ruthenium cluster catlysts {[Ru6(CO)18]2–/oxide} without the interstitial carbon and conventional metallic Ru catalysts.
Y. Izumi, T. Chihara, H. Yamazaki and Y. Iwasawa, J. Chem. Soc., Chem. Commun., 1992, 1395 DOI: 10.1039/C39920001395
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