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Issue 19, 1992
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Selective synthesis of oxygenates in the CO–H2 reaction on supported ruthenium carbido-cluster catalysts

Abstract

Supported ruthenium carbido-cluster catalysts ([Ru6C(CO)16Me]/oxide) selectively produced methanol, dimethyl ether, and formaldehyde in CO–H2, in contrast to the preferential formation of methane and hydrocarbons on supported ruthenium cluster catlysts {[Ru6(CO)18]2–/oxide} without the interstitial carbon and conventional metallic Ru catalysts.

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Article information


J. Chem. Soc., Chem. Commun., 1992, 1395-1396
Article type
Paper

Selective synthesis of oxygenates in the CO–H2 reaction on supported ruthenium carbido-cluster catalysts

Y. Izumi, T. Chihara, H. Yamazaki and Y. Iwasawa, J. Chem. Soc., Chem. Commun., 1992, 1395
DOI: 10.1039/C39920001395

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