Issue 13, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

A new route to planar-chiral cyclopentadienyl-iron(II) and -rhodium(I) complexes

Mitsunari Uno,   Katsuhiro Ando,   Nobuko Komatsuzaki  and  Shigetoshi Takahashi  

Abstract

Diastereoisomerically pure planar-chiral cyclopentadienyl-metal complexes, 3 and 4, are prepared by the reaction of the cyclopentadiene 2 having a (–)-menthyl group with FeCl2 or [Rh(cod)Cl]2(cod = cylcloocta-1,5-diene); removal of the (–)-menthyl group from 4 affords the first optically pure enantiomers, (+)-5 and (–)-5.

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Article information

DOI
https://doi.org/10.1039/C39920000964
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 964-965

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A new route to planar-chiral cyclopentadienyl-iron(II) and -rhodium(I) complexes

M. Uno, K. Ando, N. Komatsuzaki and S. Takahashi, J. Chem. Soc., Chem. Commun., 1992, 964 DOI: 10.1039/C39920000964

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