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Issue 12, 1992
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The rates of a Diels–Alder reaction in liquid and supercritical carbon dioxide

Abstract

Kinetic measurements on the Diels–Alder reaction between p-benzoquinone and cyclopenta-1,3-diene have been carried out in carbon dioxide as a medium between 25 and 40 °C; the reaction effectively occurs throughout liquid and supercritical ranges with no discontinuity and rates are about 20% greater than those in diethyl ether.

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Article information


J. Chem. Soc., Chem. Commun., 1992, 876-877
Article type
Paper

The rates of a Diels–Alder reaction in liquid and supercritical carbon dioxide

N. S. Isaacs and N. Keating, J. Chem. Soc., Chem. Commun., 1992, 876
DOI: 10.1039/C39920000876

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