Issue 9, 1992

Generation of alkylidenecarbenes by the alkenation of carbonyl compounds with lithiotrimethylsilyldiazomethane

Abstract

The reaction of carbonyl compounds and lithiotrimethylsilyldiazomethane, which generate alkylidenecarbenes, gives a terminal acetylene from an aldehyde and cyclopentene derivatives from ketones.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 721-722

Generation of alkylidenecarbenes by the alkenation of carbonyl compounds with lithiotrimethylsilyldiazomethane

S. Ohira, K. Okai and T. Moritani, J. Chem. Soc., Chem. Commun., 1992, 721 DOI: 10.1039/C39920000721

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