Issue 2, 1992

A double ionic mechanism for the Chapman-like rearrangement of imino-ethers to N-alkylmides, in the solid state or in the melt. Theoretical and experimental evidence

Abstract

Using 5-methoxy-2-aryl-1,3,4-oxadiazoles as models it was shown that the thermal rearrangement of imino-ethers to N-alkylamides proceeds through a double ionic mechanism; kinetic measurements in the solid state and in the melt give apparent activation energies that support ab initio calculated activation enthalpies.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 132-134

A double ionic mechanism for the Chapman-like rearrangement of imino-ethers to N-alkylmides, in the solid state or in the melt. Theoretical and experimental evidence

M. Dessolin, O. Eisenstein, M. Golfier, T. Prangé and P. Sautet, J. Chem. Soc., Chem. Commun., 1992, 132 DOI: 10.1039/C39920000132

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