Issue 21, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Sulphinyl-controlled formation of diastereoisomerically pure (oxadiene)tricarbonyliron(0) complexes

Arthur Ibbotson,   Alexandra M. Z. Slawin,   Susan E. Thomas,   Gary J. Tustin  and  David J. Williams  

Abstract

The sulphonyl and sulphinyl substituted oxadienes [RS(O)nCH[double bond, length half m-dash]CHC(Me)[double bond, length half m-dash]O; R = But, Ph; n= 2,1] form stable tricarbonyliron(0) complexes; the sulphinyl complexes formed are diastereoisomerically pure and the relative stereochemistry of the tricarbonyliron(0) unit and the sulphinyl substituent in the products has been determined by an X-ray crystal structure analysis of [ButS(O)CH[double bond, length half m-dash]CHC(Me)[double bond, length half m-dash]O](CO)3Fe0.

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Article information

DOI
https://doi.org/10.1039/C39910001534
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1534-1536

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Sulphinyl-controlled formation of diastereoisomerically pure (oxadiene)tricarbonyliron(0) complexes

A. Ibbotson, A. M. Z. Slawin, S. E. Thomas, G. J. Tustin and D. J. Williams, J. Chem. Soc., Chem. Commun., 1991, 1534 DOI: 10.1039/C39910001534

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