Jump to main content
Jump to site search

Issue 21, 1991
Previous Article Next Article

Sulphinyl-controlled formation of diastereoisomerically pure (oxadiene)tricarbonyliron(0) complexes

Abstract

The sulphonyl and sulphinyl substituted oxadienes [RS(O)nCH[double bond, length half m-dash]CHC(Me)[double bond, length half m-dash]O; R = But, Ph; n= 2,1] form stable tricarbonyliron(0) complexes; the sulphinyl complexes formed are diastereoisomerically pure and the relative stereochemistry of the tricarbonyliron(0) unit and the sulphinyl substituent in the products has been determined by an X-ray crystal structure analysis of [ButS(O)CH[double bond, length half m-dash]CHC(Me)[double bond, length half m-dash]O](CO)3Fe0.

Back to tab navigation

Article type: Paper
DOI: 10.1039/C39910001534
J. Chem. Soc., Chem. Commun., 1991, 1534-1536

  •   Request permissions

    Sulphinyl-controlled formation of diastereoisomerically pure (oxadiene)tricarbonyliron(0) complexes

    A. Ibbotson, A. M. Z. Slawin, S. E. Thomas, G. J. Tustin and D. J. Williams, J. Chem. Soc., Chem. Commun., 1991, 1534
    DOI: 10.1039/C39910001534

Search articles by author

Spotlight

Advertisements