The synthesis of [diphenyl(N-p-tolyl)phosphinimidoyl]bis(diphenylthiophosphinoyl)methane, its stabilized anion and a coordination complex of rhodium(I)
Abstract
The title compound was synthesized by the reaction of [Ph2P][Ph2P(S)]2CH with p-tolyl azide; its resonance-stabilized anion and a coordination complex, Rh(cod){[Ph2P(S)]2[Ph2PN(p-tol)C](cod = cycloocta-1,5-diene), of the anion were also synthesized and characterized.