SCHEDULED MAINTENANCE
Synthesis of metal-butyrolactones via insertion of a metal acyl bond into an organic ketone is demonstrated, and the crystal structure of one example is reported; labelling experiments exclude the possibility that this insertion is initiated by intramolecular attack of the enol on the acyl group.
G. Yang, G. Lee, S. Peng and R. Liu, J. Chem. Soc., Chem. Commun., 1991, 478 DOI: 10.1039/C39910000478
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