SCHEDULED MAINTENANCE
1-Bromopentyllithium 1, a typical [bromocarbenoid,] has been established to be chiral and configurationally stable at –120 °C by a test based on kinetic resolution; likewise, diastereoisomeric 1-bromoalkyllithium compounds were generated from the bromo-tin compounds 5 and 6 and found to be configurationally stable at –110 °C.
R. W. Hoffmann, T. Ruhland and M. Bewersdorf, J. Chem. Soc., Chem. Commun., 1991, 195 DOI: 10.1039/C39910000195
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