Issue 3, 1991

A novel Rh–B σ bond. Crystal structure of [N(CH3)4][RhCl{7,8-µ-S(CH2CH2)S-C2B9H10}{σ-7,8-µ-S(CH2CH2)S-C2B9H9}]

Abstract

The complex [N(CH3)4][RhCl{7,8-µ-S(CH2CH2)S–C2B9H10}{σ-7,8-µ-S(CH2CH2)S–C2B9H9}] is an octahedral Rh(III) complex; the sixth coordination site is occupied by a σ-bond B–Rh in this first example of B(3)–Rh coordination.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 192-193

A novel Rh–B σ bond. Crystal structure of [N(CH3)4][RhCl{7,8-µ-S(CH2CH2)S-C2B9H10}{σ-7,8-µ-S(CH2CH2)S-C2B9H9}]

F. Teixidor, A. Romerosa, C. Viñas, J. Rius, C. Miravittles and J. Casabó, J. Chem. Soc., Chem. Commun., 1991, 192 DOI: 10.1039/C39910000192

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