Issue 3, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Intrazeolite metal carbonyl kinetics: 12CO substitution in Mo(12CO)6-Na56Y by PMe3 and 13CO

Geoffrey A. Ozin,   Saim Özkar,   Heloise O. Pastore,   Anthony J. Poë  and  Eduardo J. S. Vichi  

Abstract

The first kinetic study is reported for archetypical substitution reactions of PMe3 and 13CO with the well defined intrazeolite system, Mo(12CO)6-Na56Y, for which excellent isosbestic points and first order behaviour are obtained, the activation parameters indicate a highly ordered ‘supramolecular’ transition state consisting of activated Mo(12CO)6 and PMe3 or 13CO all anchored to the Na+ ions in the α-cage of the host lattice.

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Article information

DOI
https://doi.org/10.1039/C39910000141
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 141-143

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Intrazeolite metal carbonyl kinetics: 12CO substitution in Mo(12CO)6-Na56Y by PMe3 and 13CO

G. A. Ozin, S. Özkar, H. O. Pastore, A. J. Poë and E. J. S. Vichi, J. Chem. Soc., Chem. Commun., 1991, 141 DOI: 10.1039/C39910000141

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