Issue 3, 1991

Palladium-assisted rearrangement of HC(O)C6H2(OMe)3-3,4,5 to HC(O)C6H2(OMe)3-2,3,4. X-Ray structures of [PdR(PPh3)(bipy)](CF3SO3)[R = C6H(CHO)-6,(OMe)3-2,3,4 and C6H(CHO)-2,(OMe)3-3,4,5; bipy = 2,2′-bipyridyl]

Abstract

The anionic complex [Pd2R2Cl2(µ-Cl)2]2–{1, R = C6H(CHO)-6,(OMe)3 2,3,4} and the neutral [Pd2R′2(µ-Cl)2]{2, R′= C6H(CHO)-2,(OMe)3-3,4,5} are both obtained by reaction of HgR2 with appropriate palladium precursors; the isomerization of R to R′ was confirmed by X-ray studies of the derivatives [PdR(PPh3)(bipy)](CF3SO3)5 and [PdR′(PPh3)(bipy)](CF3SO3)5′.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 137-139

Palladium-assisted rearrangement of HC(O)C6H2(OMe)3-3,4,5 to HC(O)C6H2(OMe)3-2,3,4. X-Ray structures of [PdR(PPh3)(bipy)](CF3SO3)[R = C6H(CHO)-6,(OMe)3-2,3,4 and C6H(CHO)-2,(OMe)3-3,4,5; bipy = 2,2′-bipyridyl]

J. Vicente, J. Abad, M. Stiakaki and P. G. Jones, J. Chem. Soc., Chem. Commun., 1991, 137 DOI: 10.1039/C39910000137

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements