Issue 15, 1990
From the journal:

Journal of the Chemical Society, Chemical Communications

Electron-deficient group IV metal alkyl cations, and the synthesis of Zr(CH2Ph)3(η6-C6H5)BPh3: a fluxional arene π-complex of a d0 metal

Manfred Bochmann,   Gerhard Karger  and  Andrew J. Jaggar  

Abstract

Mild protolysis of titanium and zirconium alkyls provides a general route to solvent or anion stabilised 6- and 10-electron cationic group IV alkyl complexes, including the first halide-free arene complex of a d0 metal.

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Article information

DOI
https://doi.org/10.1039/C39900001038
Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1038-1039

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Electron-deficient group IV metal alkyl cations, and the synthesis of Zr(CH2Ph)3(η6-C6H5)BPh3: a fluxional arene π-complex of a d0 metal

M. Bochmann, G. Karger and A. J. Jaggar, J. Chem. Soc., Chem. Commun., 1990, 1038 DOI: 10.1039/C39900001038

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