The N2 elimination from diazo acetic acid esters, heterogeneously catalysed by Raney Nickel, yields as chemidesorbed main product up to 93% malefic acid diester, cis-stereoselectivity is observed and additional methyl/ethyl ester crossing experiments provide evidence for dipod-chemisorbed surface carbene intermediates.
H. Bock and H. P. Wolf, J. Chem. Soc., Chem. Commun., 1990, 690 DOI: 10.1039/C39900000690
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...