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Issue 23, 1989
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Oxidative addition of Si–Cl bonds to electron-rich IrI complexes

Abstract

Si–Cl bonds undergo facile, rarely observed oxidative addition to (C8H14)Ir(PMe3)3Cl (1) to yield, when MeSiCl3 is used, the crystallographically characterized mer-Ir(PMe3)3(Cl)2(SiMeCl2), exhibiting a short Ir–Si bond; reaction of (1) and of other electron-rich IrI complexes with Me3SiCl yields Ir–H complexes, probably arising from a rare silyl β-hydride elimination process.

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Article type: Paper
DOI: 10.1039/C39890001826
Citation: J. Chem. Soc., Chem. Commun., 1989,0, 1826-1827

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    Oxidative addition of Si–Cl bonds to electron-rich IrI complexes

    A. A. Zlota, F. Frolow and D. Milstein, J. Chem. Soc., Chem. Commun., 1989, 0, 1826
    DOI: 10.1039/C39890001826

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