SCHEDULED MAINTENANCE
The reaction between [Fe(C5Me5)(CO)2Br] and C6Et6 in the presence of AlCl3 does not give [Fe(C5Me5)(C6Et6)]+ but, in the prsence of protic impurities, [Fe(C5Me5)(C6Et5H)]+ is the only cation formed; the X-ray crystal structure of its PF6– salt shows that all Et substituents are distal and a σ intermediate is proposed for the complexation.
J. Hamon, J. Saillard, L. Toupet and D. Astruc, J. Chem. Soc., Chem. Commun., 1989, 1662 DOI: 10.1039/C39890001662
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