Issue 19, 1989

Thermal rearrangements of benzobicyclononatrienes (1,4-propeno-1,4-dihydronaphthalenes) to benzobarbaralanes; intramolecular Diels–Alder rather than intramolecular ene reactions

Abstract

The rearrangement of (1) to (2) involves the sequence (1)→(4)→(7)→(8)→(2) rather than the intramolecular ene process (1; arrows) earlier proposed; other examples of this process and the walk rearrangement of type (4)→(7) are described.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1481-1483

Thermal rearrangements of benzobicyclononatrienes (1,4-propeno-1,4-dihydronaphthalenes) to benzobarbaralanes; intramolecular Diels–Alder rather than intramolecular ene reactions

D. W. Jones, J. Chem. Soc., Chem. Commun., 1989, 1481 DOI: 10.1039/C39890001481

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