Issue 18, 1989

Thiols as polarity reversal catalysts for hydrogen-atom transfer from organosilanes to alkyl radicals: reduction of alkyl halides by triethylsilane

Abstract

Triethylsilane reduces alkyl halides to alkanes under mild conditions in the presence of thiols, which act as polarity reversal catalysts for hydrogen-atom transfer from the silane to an alkyl radical.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1387-1388

Thiols as polarity reversal catalysts for hydrogen-atom transfer from organosilanes to alkyl radicals: reduction of alkyl halides by triethylsilane

R. P. Allen, B. P. Roberts and C. R. Willis, J. Chem. Soc., Chem. Commun., 1989, 1387 DOI: 10.1039/C39890001387

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