Issue 17, 1989

Carbon/poly {pyrrole-[(C5Me5)RhIII(bpy)Cl]+} modified electrodes; a molecularly-based material for hydrogen evolution (bpy = 2,2′-bipyridine)

Abstract

A rhodium(III) complex containing a 2,2′-bipyridine ligand substituted with pyrrole groups has been anodically electropolymerized on either a Pt or a C electrode; the polymer attached to C acts as an efficient molecularly-based cathode material for hydrogen evolution in aqueous solution (pH 1).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1259-1261

Carbon/poly {pyrrole-[(C5Me5)RhIII(bpy)Cl]+} modified electrodes; a molecularly-based material for hydrogen evolution (bpy = 2,2′-bipyridine)

S. Cosnier, A. Deronzier and N. Vlachopoulos, J. Chem. Soc., Chem. Commun., 1989, 1259 DOI: 10.1039/C39890001259

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