Issue 17, 1989
From the journal:

Journal of the Chemical Society, Chemical Communications

The remarkable thermal stability of benzyl[tris(dimethylphenylsily)methyl]mercury. How can a bulky ligand stabilize an organometallic compound towards unimolecular dissociation?

Colin Eaborn,   Karen L. Jones,   J. David Smith  and  Kayumars Tavakkoli  

Abstract

Only at 245 °C is the rate of the thermal decomposition of (Me2PhSi)3CHgCH2Ph in diphenyl ether comparable with that of (PhCH2)2Hg at 150 °C; it is suggested that this may be because within the collisionally energized molecule there is only slow transmission of energy through the metal atom.

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Article information

DOI
https://doi.org/10.1039/C39890001201
Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1201-1202

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The remarkable thermal stability of benzyl[tris(dimethylphenylsily)methyl]mercury. How can a bulky ligand stabilize an organometallic compound towards unimolecular dissociation?

C. Eaborn, K. L. Jones, J. D. Smith and K. Tavakkoli, J. Chem. Soc., Chem. Commun., 1989, 1201 DOI: 10.1039/C39890001201

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