The nitrogen atom of [1-(η5-C5Me5)-4-(NEt2)isocloso-1-RhB10H9] is planar, the N(4)–B(4) bond is short, and there is restricted rotation about this bond (ΔG‡272ca. 54kJ mol–1), all implying significant N→B π-donation into the cluster.
E. J. Ditzel, X. L. R. Fontaine, N. N. Greenwood, J. D. Kennedy and M. Thornton-Pett, J. Chem. Soc., Chem. Commun., 1989, 1115 DOI: 10.1039/C39890001115
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