Issue 20, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

Regiospecific lithiation of permethylated (η6-tricarbonylchromium)phenylacetyl(tetracarbonyl)iron anion: a versatile method for the α,α′-ortho-bifunctionalization of hexamethylbenzene

Jean-Jacques Yaouanc,   Jean-Claude Clement  and  Hervé des Abbayes  

Abstract

Me6C6{Cr(CO3)} has been converted into α,α′-ortho-bifunctionalized hexamethylbenzenes (RCH2)(R′COCH2)Me4C6 in high yields, by a sequence involving lithiation, reaction with Fe(CO)5, a further lithiation, and two sequential alkylation reactions.

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Article information

DOI
https://doi.org/10.1039/C39880001379
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1379-1380

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Regiospecific lithiation of permethylated (η6-tricarbonylchromium)phenylacetyl(tetracarbonyl)iron anion: a versatile method for the α,α′-ortho-bifunctionalization of hexamethylbenzene

J. Yaouanc, J. Clement and H. des Abbayes, J. Chem. Soc., Chem. Commun., 1988, 1379 DOI: 10.1039/C39880001379

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