Issue 19, 1988

Insertion of terminal phosphinidene complexes into a nickel–carbon bond; X-ray crystal structure of the complex [CpNi{η-Me-P–CPh[double bond, length half m-dash]CPh–NiCp}P–W(CO)5](Cp = cyclopentadienyl)

Abstract

New phosphametallacyclobutene complexes (4a–c) have been obtained by the reactions of (7-methyl-7-phosphanorbornadiene)pentacarbonyltungsten (1) with some alkynebis(cyclopentadienylnickel) complexes.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1325-1326

Insertion of terminal phosphinidene complexes into a nickel–carbon bond; X-ray crystal structure of the complex [CpNi{η-Me-P–CPh[double bond, length half m-dash]CPh–NiCp}P–W(CO)5](Cp = cyclopentadienyl)

R. de Vaumas, A. Marinetti, F. Mathey and L. Ricard, J. Chem. Soc., Chem. Commun., 1988, 1325 DOI: 10.1039/C39880001325

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