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Issue 18, 1988
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A new arsenic-rich polyanion. Synthesis and structure of [(CH3C(CH2PPh2)3)NiI]2[As6I8]

Abstract

The reaction of AsI3 with [Ni(H2O)6](ClO4)2 and CH3C(CH2PPh2)3 yields the new arsenic iodide anion [As6I8]2– the structure of which has been determined by X-ray crystallography.

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Article information


J. Chem. Soc., Chem. Commun., 1988, 1241-1242
Article type
Paper

A new arsenic-rich polyanion. Synthesis and structure of [(CH3C(CH2PPh2)3)NiI]2[As6I8]

C. A. Ghilardi, S. Midollini, S. Moneti and A. Orlandini, J. Chem. Soc., Chem. Commun., 1988, 1241
DOI: 10.1039/C39880001241

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