Issue 14, 1988

Facile pathway-defined fluxional cluster isomerization in ten-vertex closo-2,1,6-metalladicarbaboranes of ruthenium and rhodium

Abstract

Multi-element n.m.r. spectroscopy allied with deuterium labelling and single-crystal X-ray diffraction analysis revels fluxionality within [2-(η6-C6Me6)-closo-2,1,6-RuC2B7H9] and [2-(η5-C5Me5)-closo-2,1,6-RhC2B7H9] that results in enantiomeric exchange (between the 2,1,6 and 2,1,9 forms)via defined diamond–square–diamond pathways.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 974-975

Facile pathway-defined fluxional cluster isomerization in ten-vertex closo-2,1,6-metalladicarbaboranes of ruthenium and rhodium

M. Bown, T. Jelínek, B. Štíbr, S. Heřmánek, X. L. R. Fontaine, N. N. Greenwood, J. D. Kennedy and M. Thornton-Pett, J. Chem. Soc., Chem. Commun., 1988, 974 DOI: 10.1039/C39880000974

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