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Issue 5, 1988
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Ring tilting and the barriers to rotation of arene rings π-bonded to transition metals

Abstract

Restricted rotation of the arene ring in complexes of the type (arene)M(CO)3-x(SiCl3)x(M = Re, x= 1; M = Ru, Os, x= 2) appears to occur when the ring is prevented from tilting by the presence of two bulky groups on both the arene ring and the transition metal.

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Article information


J. Chem. Soc., Chem. Commun., 1988, 362-364
Article type
Paper

Ring tilting and the barriers to rotation of arene rings π-bonded to transition metals

X. Hu, J. Duchowski and R. K. Pomeroy, J. Chem. Soc., Chem. Commun., 1988, 362
DOI: 10.1039/C39880000362

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