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Issue 2, 1988
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Intramolecular condensation of co-ordinated acetonitrile in a binuclear complex of cobalt(III). X-Ray crystallographic analysis of Na[(NH3)3Co{µ-OH, µ-NH2, µ-MeC(NH)2}Co(NH3)3](S2O6)2·H2O

Abstract

The dimer complex [(NH3)4Co(µ-OH, µ-NH2)Co(NH3)4](CF3SO3)4 in acetonitrile generates an acetamidino complex which bridges both Co atoms, presumably as a result of substitution of acetonitrile and intramolecular attack by a co-ordinated amido ion.

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J. Chem. Soc., Chem. Commun., 1988, 119-121
Article type
Paper

Intramolecular condensation of co-ordinated acetonitrile in a binuclear complex of cobalt(III). X-Ray crystallographic analysis of Na[(NH3)3Co{µ-OH, µ-NH2, µ-MeC(NH)2}Co(NH3)3](S2O6)2·H2O

L. Roecker, A. M. Sargeson and A. C. Willis, J. Chem. Soc., Chem. Commun., 1988, 119
DOI: 10.1039/C39880000119

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