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Issue 1, 1988
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Unusually ready cleavage of an S–Cα bond in sterically crowded sulphoxides

Abstract

Oxidation of sterically crowded sulphides containing a 2,4,6-tri-t-butylphenyl group or its Dewar benzene analogue affords unusually unstable sulphoxides which undergo ready heterolytic S–Cα cleavage to give indan derivatives and sulphenic acids.

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Article type: Paper
DOI: 10.1039/C39880000040
J. Chem. Soc., Chem. Commun., 1988, 40-41

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    Unusually ready cleavage of an S–Cα bond in sterically crowded sulphoxides

    R. Okazaki, T. Ishida and N. Inamoto, J. Chem. Soc., Chem. Commun., 1988, 40
    DOI: 10.1039/C39880000040

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