The 1,3-dipolar cycloaddition of 2-diazopropane with trimethyl[3-(p-tolylsulphonyl-2,5-norbornadiene-2-yl)]silane occurs across the unsubstituted double bond; regiochemical control can be attributed to steric rather than to stereoelectronic factors.
A. Padwa and M. W. Wannamaker, J. Chem. Soc., Chem. Commun., 1987, 1742 DOI: 10.1039/C39870001742
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