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Issue 14, 1987
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Regioselective one pot approach to aminodeoxy sugars via aminosilanes

Abstract

A novel one-step synthesis of regioisomerically pure aminodeoxy sugars (6)–(11) has been achieved by trans-diaxial cleavage of the oxirane ring in 2,3-anhydro sugars (1)–(5) with N,N-diethyltrimethylsilylamine or its N,N-dimethyl analogue, using AlCl3 as catalyst; the reagents work under mild conditions and avoid the difficulties which sometimes are encountered in ring-opening reactions of epoxy sugars.

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Article information


J. Chem. Soc., Chem. Commun., 1987, 1073-1074
Article type
Paper

Regioselective one pot approach to aminodeoxy sugars via aminosilanes

A. Malik, N. Kazmi, A. Q. Khan and Z. Ahmad, J. Chem. Soc., Chem. Commun., 1987, 1073
DOI: 10.1039/C39870001073

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