Issue 12, 1987

Asymmetric synthesis of the spiroacetal fragment of milbemycin E

Abstract

Spiro-acetals (17) and (21) have been synthesized from methyl α-D-glucopyranoside (11), via the 6-chloro-4,6-dideoxygalactopyranoside (10), the epoxy-dithiane (8), and the open-chain dithianes (16) and (20).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 877-880

Asymmetric synthesis of the spiroacetal fragment of milbemycin E

G. Khandekar, G. C. Robinson, N. A. Stacey, P. G. Steel, E. J. Thomas and S. Vather, J. Chem. Soc., Chem. Commun., 1987, 877 DOI: 10.1039/C39870000877

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