Reaction of di-t-butyl peroxide, (ButO)2, with CuI chloride species gives CuII alkoxy chlorides which are intermediates in the oxidative carbonylation reaction of alcohols to dialkyl carbonate, oxalate, or succinate esters and evidence is presented that these reactions do not involve free radicals.
G. E. Morris, D. Oakley, D. A. Pippard and D. J. H. Smith, J. Chem. Soc., Chem. Commun., 1987, 411 DOI: 10.1039/C39870000411
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