Issue 2, 1987

A new approach to linear tetracycles via Michael reactions of quinizarinquinone with O-silylated ketene acetals

Abstract

The Michael-type reaction of quinizarinquinone and 1-ethoxy-1-(trimethylsiloxy)buta-1,3-diene followed by Lewis acid-catalysed [1,5] sigmatropic rearrangement and Friedel–Crafts cyclisation provides a new route to variously functionalized tetracycles.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 102-104

A new approach to linear tetracycles via Michael reactions of quinizarinquinone with O-silylated ketene acetals

K. Hayakawa, M. Aso and K. Kanematsu, J. Chem. Soc., Chem. Commun., 1987, 102 DOI: 10.1039/C39870000102

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