Issue 12, 1986

Novel alkylmetal hydroxides. The crystal and molecular structures of bis(µ-hydroxy)-bis{tris(dimethylphenylsilyl)methylzinc}, [{Me2PhSi)3CZnOH}2] and µ4-oxohexa(µ-hydroxy)tetrakis{tris(trimethylsilyl)methylindium}, [O{(Me3Si)3Cln}4(OH)6]

Abstract

The compounds [{(Me2PhSi)3CZnOH}2] and [O{(Me3Si)3Cln}4(OH)6] have been shown by X-ray diffraction to have structures based on four-membered M2O2-rings (M = Zn or ln).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 908-909

Novel alkylmetal hydroxides. The crystal and molecular structures of bis(µ-hydroxy)-bis{tris(dimethylphenylsilyl)methylzinc}, [{Me2PhSi)3CZnOH}2] and µ4-oxohexa(µ-hydroxy)tetrakis{tris(trimethylsilyl)methylindium}, [O{(Me3Si)3Cln}4(OH)6]

S. S. Al-Juaid, N. H. Buttrus, C. Eaborn, P. B. Hitchcock, A. T. L. Roberts, J. D. Smith and A. C. Sullivan, J. Chem. Soc., Chem. Commun., 1986, 908 DOI: 10.1039/C39860000908

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