Treatment of β-epoxy-sulphone, -sulphoxide, and -ester with Grignard reagents and copper(I) iodide in diethyl ether–tetrahydrofuran at low temperature leads to rapid ring opening without loss of chirality.
R. Tanikaga, K. Hosoya and A. Kaji, J. Chem. Soc., Chem. Commun., 1986, 836 DOI: 10.1039/C39860000836
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