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The i.r. spectrum of Al(CO)2, observed in deposits of Al atoms and CO in adamantane at 77 K, has a symmetric CO stretching mode at 1985 cm–1 and antisymmetric CO stretching mode at 1903.8 cm–1; there is i.r. evidence for the formation of Al2CO and Al2(CO)4 in this system.
J. H. B. Chenier, C. A. Hampson, J. A. Howard and B. Mile, J. Chem. Soc., Chem. Commun., 1986, 730 DOI: 10.1039/C39860000730
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