Issue 8, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Determination of the absolute configuration and optical purity of [(η5-C5H5)Fe(CO)(PPh3)COMe]; X-ray crystal structure of (R)-{(η5-C5H5)Fe(CO)(PPh3)COCH2CH2O[(R)-menthyl]}

Stephen G. Davies,   Isabelle M. Dordor-Hedgecock,   Kevin H. Sutton,   Jonathan C. Walker,   Christopher Bourne,   Richard H. Jones  and  Keith Prout  

Abstract

The enantiomeric purities of (R)-(–)-[(η5-C5H5)Fe(CO)(PPh3)COMe](1)[α]54622–288°(c 0.04, C6H6) and S-(+)-(1)[α]54622+288°(c 0.04, C6H6) are established by two independent methods and the absolute configurations assigned by an X-ray structure analysis of (R)-{(η5-C5H5)Fe(CO)(PPh3)COCH2CH2O [(R)-menthyl]}.

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Article information

DOI
https://doi.org/10.1039/C39860000607
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 607-609

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Determination of the absolute configuration and optical purity of [(η5-C5H5)Fe(CO)(PPh3)COMe]; X-ray crystal structure of (R)-{(η5-C5H5)Fe(CO)(PPh3)COCH2CH2O[(R)-menthyl]}

S. G. Davies, I. M. Dordor-Hedgecock, K. H. Sutton, J. C. Walker, C. Bourne, R. H. Jones and K. Prout, J. Chem. Soc., Chem. Commun., 1986, 607 DOI: 10.1039/C39860000607

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