SCHEDULED MAINTENANCE
Diels–Alder addition of an ethylene equivalent to steroidal 14,16-dien-17-yl acetates provides a novel synthetic route to 14α-formylestrone, and, hence, to the 14α-hydroxymethyl and 14α-methyl analogues.
J. R. Bull and R. I. Thomson, J. Chem. Soc., Chem. Commun., 1986, 451 DOI: 10.1039/C39860000451
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