Issue 4, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis, characterization, and properties of the pentamethylcyclopentadienyltetra-carbonylmetallates(0) of titanium and zirconium. Anionic and carbocyclic derivatives of zerovalent group 4 carbonyls, (C5Me5)M(CO)4–

Beatrice A. Kelsey  and  John E. Ellis  

Abstract

Reductive carbonylations at atmospheric pressure of (C5Me5)MCl3(M = Ti and Zr), conducted at low temperature, provide thermally robust and crystalline products of the general formula [Et4N][(C5Me5)M(CO)4], which contain the first examples of carbonyl anions of titanium and zirconium.

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Article information

DOI
https://doi.org/10.1039/C39860000331
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 331-332

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Synthesis, characterization, and properties of the pentamethylcyclopentadienyltetra-carbonylmetallates(0) of titanium and zirconium. Anionic and carbocyclic derivatives of zerovalent group 4 carbonyls, (C5Me5)M(CO)4–

B. A. Kelsey and J. E. Ellis, J. Chem. Soc., Chem. Commun., 1986, 331 DOI: 10.1039/C39860000331

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