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Issue 23, 1985
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Type 3 copper model chemistry. Dioxygen activation by binuclear two-co-ordinate copper(I) complexes derived from L-histidine and L-Nτ-methylhistidine

Abstract

The reaction of dioxygen with the binuclear two-co-ordinate copper(I) complexes derived from the condensation of benzene-1,3-dicarbaldehyde and two molecules of L-histidine methyl ester or L-Nτ-methylhistidine methyl ester occurs with hydroxylation of the aromatic nucleus at position 2, producing binuclear phenoxy-bridged copper(II) complexes.

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Article information


J. Chem. Soc., Chem. Commun., 1985, 1668-1669
Article type
Paper

Type 3 copper model chemistry. Dioxygen activation by binuclear two-co-ordinate copper(I) complexes derived from L-histidine and L-Nτ-methylhistidine

L. Casella and L. Rigoni, J. Chem. Soc., Chem. Commun., 1985, 1668
DOI: 10.1039/C39850001668

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