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Issue 22, 1985
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The binding of cyclobutane-1,1-dicarboxylatodiamineplatinum(II) by α-cyclodextrin in aqueous solution

Abstract

Microcalorimetry and 1H n.m.r. spectroscopy have established that Pt(NH3)2(CBDCA)(CBDCA = cyclobutane-1,1-dicaboxylato) and α-cylodextrin (α-CD)form a 1:1 adduct in water with a standard free energy change (–ΔG) in the region of 10.4–13.0 kJ mol–1 at 22–25 °C.

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Article information


J. Chem. Soc., Chem. Commun., 1985, 1600-1602
Article type
Paper

The binding of cyclobutane-1,1-dicarboxylatodiamineplatinum(II) by α-cyclodextrin in aqueous solution

D. R. Alston, T. H. Lilley and J. F. Stoddart, J. Chem. Soc., Chem. Commun., 1985, 1600
DOI: 10.1039/C39850001600

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