Low molecular-weight derivatives obtained during ring-opening polymerization of norbornene using W(CO)3Cl2(AsPh3)2 as catalyst indicate that a 2,3-hydrogen shift is a key step for the formation of the carbene initiator.
L. Bencze, A. Kraut-Vass and L. Prókai, J. Chem. Soc., Chem. Commun., 1985, 911 DOI: 10.1039/C39850000911
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