Issue 12, 1985

Rearrangement of an o-substituted phenyl radical by 1,7-hydrogen atom migration

Abstract

Formation of the azetidinonethiol (10) by treatment of the aryl halide (6) with tributylstannane involves an unusually rapid 1,7-hydrogen atom transfer followed by β-fission of the resultant radical (8).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 797-798

Rearrangement of an o-substituted phenyl radical by 1,7-hydrogen atom migration

A. L. J. Beckwith and D. R. Boate, J. Chem. Soc., Chem. Commun., 1985, 797 DOI: 10.1039/C39850000797

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